高分子物理：結(jié)構(gòu)與性能背后的概念

出版說明
推薦序
preface（前言）
preface to the first edition/第1版前言
1constitution and architecture of chains/鏈的組成與構(gòu)造1
2single chain conformations /單鏈構(gòu)象15
2.1rotational isomeric states /旋轉(zhuǎn)異構(gòu)態(tài)15
2.2helices/螺旋19
2.3coils /線團22
2.3.1the ideal chain/理想鏈26
2.3.2the expanded chain/膨脹鏈45
2.4the persistent chain/持續(xù)鏈55
2.5the ising chain/ 伊辛鏈59
3polymer solutions /聚合物溶液69
3.1dilute and semidilute solutions/稀溶液與半稀溶液70
3.1.1osmotic pressure/滲透壓71
3.2screening of excluded volume forces/排除體積力的屏蔽82
3.3polyelectrolyte solutions/聚電解質(zhì)溶液89
3.3.1condensation and screening of charges /電荷的團聚與屏蔽89
3.3.2chain stretching, salt effects and interchainordering/鏈伸展、鹽效應(yīng)與鏈間序95
3.3.3osmotic pressure/滲透壓100
4polymer blends and block copolymers/共混物與嵌段共聚物105
4.1the flory?huggins treatment of polymermixtures/聚合物混合物的flory?huggins處理方法106
4.1.1phase diagrams: upper and lower miscibilitygap/相圖：上臨界與下臨界混溶間隙117
4.2phase separation mechanisms/相分離機理122
4.3critical fluctuations and spinodaldecomposition/臨界漲落與旋節(jié)線分解129
4.3.1critical scattering/臨界散射132
4.3.2decomposition kinetics/分解動力學(xué)143
4.4block copolymer phases/嵌段共聚物的相結(jié)構(gòu)151
4.4.1layered structures/層狀結(jié)構(gòu)155
4.4.2pretransitional phenomena/前轉(zhuǎn)變現(xiàn)象157
5the semicrystalline state/半結(jié)晶態(tài)165
5.1structure characteristics/結(jié)構(gòu)特征167
5.1.1morphological elements /基本形態(tài)167
5.1.2structure parameters/結(jié)構(gòu)參數(shù)173
5.2kinetics of crystallization and melting/結(jié)晶與熔融動力學(xué)181
5.3laws for the structure development/結(jié)構(gòu)變化規(guī)律190
5.3.1the multistage model/多階段模型199
5.4mechanisms of secondary crystallization/二級結(jié)晶機理205
5.4.1the insertion mode/插層模式208
5.4.2surface crystallization and melting/表面結(jié)晶與熔融212
5.5crystallization from oriented melts/取向熔體結(jié)晶216
6mechanical and dielectric response/力學(xué)與介電響應(yīng)223
6.1response functions/響應(yīng)函數(shù)224
6.1.1viscoelasticity/粘彈性224
6.1.2orientational polarization/取向極化228
6.1.3general relationships/通用公式229
contents6.2relaxatory modes/松弛模式236
6.2.1single?time relaxation process/單時間松弛過程237
6.2.2retardation and relaxation time spectra/推遲與松弛時間242
6.3specific relaxation processes and flow behavior/具體松弛過程與流動行為245
6.3.1local processes/局部過程246
6.3.2glass?rubber transition and melt flow/玻璃?橡膠轉(zhuǎn)變與熔體流動250
6.3.3the glass transition temperature/玻璃化轉(zhuǎn)變溫度269
6.3.4relaxation in partially crystalline systems/半晶體系中的松弛277
7conjugated polymers/共軛聚合物287
7.1electrooptic activity/光電活性289
7.1.1excitons and free charges/激發(fā)與自由電荷289
7.1.2electroluminescence/電發(fā)光297
7.2effects of doping/摻雜效應(yīng)302
7.2.1electrical conductivity/電導(dǎo)率302
7.2.2magnetism and reflectivity/磁性與反射率306
8microscopic dynamics/微觀運動學(xué)313
8.1the fluctuation?dissipation theorem/漲落?耗散原理313
8.2the rouse model/rouse模型317
8.2.1stress relaxation/應(yīng)力松弛325
8.2.2the dielectric normal mode /介電基準(zhǔn)模式330
8.3entanglement effects in polymer melts/聚合物熔體中的纏結(jié)效應(yīng)333
8.3.1the reptation model/爬行模型338
8.4solution viscosities/溶液粘度 343
8.4.1neutral polymers: hydrodynamicinteraction/中性聚合物：流體力學(xué)作用344
8.4.2polyelectrolytes: coulomb interaction/聚電解質(zhì)：靜電作用 352
9non?linear mechanics /非線性力學(xué)357
9.1rubber elasticity/橡膠彈性361
9.1.1the fixed junction model of ideal rubbers/理想橡膠的固定結(jié)點模型364
9.1.2the cauchy strain tensor/ cauchy應(yīng)變張量371
9.1.3finger?s constitutive equation/ finger本構(gòu)方程376
9.2swelling of neutral and electrolytic gels/中性與電解質(zhì)凝膠的溶脹384
9.3non?newtonian melt flow/非牛頓熔體的流動390
9.3.1rheological material functions /流變材料函數(shù)391
9.3.2the lodge liquid/ lodge液體398
9.3.3the stress?optical rule/應(yīng)力?光學(xué)規(guī)則404
10deformation, yielding and fracture/形變、屈服與斷裂415
10.1shear deformation in semicrystallinepolymers/半晶聚合物中的剪切形變418
10.1.1critical strains/臨界應(yīng)變418
10.1.2constituents of the drawing stress/拉伸應(yīng)力的成分426
10.1.3the mechanics of neck formation/細頸形成機理429
10.1.4fibrillar state of order/纖維化有序態(tài)435
10.2crazing/銀紋 444
10.3brittle fracture/脆性斷裂450
10.3.1linear fracture mechanics /線性斷裂力學(xué)453
10.3.2the slow mode of crack growth/裂縫生長的緩慢模式455
ascattering experiments/散射實驗463
a.1fundamentals/基本概念463
a.1.1basic equations/基本方程464
a.1.2time?resolved scattering experiments/時間分解的散射實驗468
a.2absolute intensities/絕對強度471
a.3low angle scattering properties/小角散射性質(zhì)474
a.3.1guinier?s law/ guinier公式474
a.3.2forward scattering/前散射476
a.4special polymer systems/特種聚合物體系477
a.4.1binary mixtures and block copolymers/二元混合物與嵌段共聚物477
a.4.2two?phase layer systems/兩相層狀體系484
bglossary of symbols/術(shù)語與符號493
cbibliography/參考書目501
references/參考文獻505
index/索引